These were never supported in IE/Edge, and were dropped in Chrome 40 (2015-01-21) and Firefox 62 (2018-09-05). As such, since 2018 we've been the only browser engine to support these. While in some ways this has been supplanted by CSS Typed OM (see Bug 175733), Firefox nevertheless dropped support without adding support for CSS Typed OM, hence I don't think it makes sense to be the outlier and the only browser supporting these APIs.
Others have informed that some applications make use of these APIs (including via WK1), as such we're probably (at least in the short-term) limited to putting these behind a flag.
<rdar://problem/82922468>
At least currently, CSSPrimitiveValue is used by fingerprint.js to detect WebKit: https://github.com/fingerprintjs/fingerprintjs/blob/09d11794dfc8da0365983bdbe638b78e2977cfd4/src/utils/browser.ts#L77
*** Bug 244906 has been marked as a duplicate of this bug. ***